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Frontier science and challenges on offshore carbon storage

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 7, doi: 10.1007/s11783-023-1680-6

Abstract:

● The main direct seal up carbon options and challenges are reviewed.

Keywords: Offshore carbon storage     Direct CO<sub>2sub> injection     CO<sub>2sub>-CH<sub>4sub> replacement     CO<sub>2sub>-EOR     CCS hubs     CO<sub>2sub> transport    

Economic Development Models of Gas Condensate Reservoir

Liu Tingyuan

Strategic Study of CAE 2001, Volume 3, Issue 3,   Pages 85-91

Abstract: condensate reservoirs, including reinjection with 75% dry gas recycling, dumpflooding of gas, nitrogen injection, water injection, water and gas alternating injection, C〇<sub>2sub> injection, etc.

Keywords: gas condensate reservoir     development model     gas injection     nitrogen injection     water injection     CO <sub>2sub> injection     economic    

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

Frontiers in Energy 2023, Volume 17, Issue 3,   Pages 428-445 doi: 10.1007/s11708-023-0865-9

Abstract: For the core flooding tests, pure gas injection showed that the breakthrough time of CO<sub>2sub> was>2sub> gas injection was approximately 44.09%, while the Keywords: shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO<sub>2sub> geological    

Experimental study on the CO<sub>2sub> foam injecting way of profile control and flooding in heterogeneous

Zhao Jinsheng,Tan Junling,Gu Zhengfu,Liu Xiaochun

Strategic Study of CAE 2012, Volume 14, Issue 11,   Pages 88-93

Abstract: the foaming agent optimization result, using parallel cores with approximate permeability contrast,CO2foam flooding experiment was simulated through 2 injection way.The experiment result showed that underground foaming way, CO2 and the foaming agent injected alternatelyThe optimal injection slug combination was first 0.2 PV (pore volume) foaming agent solution and then0.4 PV CO2 gas, and the total injected volume was 0.6 PV.

Keywords: heterogeneous reservoirs     CO<sub>2sub> foam     profile control and flooding     injection parameter     experimental    

Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 6,   Pages 863-870 doi: 10.1007/s11783-013-0618-9

Abstract: Combustion-generated hydrogen chloride (HCl) is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual-layer granular bed filter, at gas temperatures of 500°C–700°C and (Ca)/ (Cl)molar ratios of 1.0–5.0 using the silver nitrate titration method by dry adsorbent powders Ca(OH) . Mainly, the adsorption efficiency of HCl and utilization efficiency of Calcium were studied, by varying relevant factors including (Ca)/ (Cl), temperature, feeding method, water vapor and CO . With a relatively higher HCl concentration of 1000 ppm, the experimental results revealed that 600°C may be the optimum temperature for HCl adsorption when optimum (Ca)/ (Cl) was 2.5 in our tests. The results also demonstrated that the feeding at a constant pressure was more effective, and the HCl adsorption efficiency could rapidly reach over 90% with (Ca)/ (Cl) = 2.5 at 600°C. Furthermore, the HCl adsorption efficiency was found to be slightly promoted by water vapor, while could be impeded by CO , and the utilization efficiency of calcium could be up to 74.4% without CO , while was only 36.8% with CO when (Ca)/ (Cl) was 2.5 at 600°C.

Keywords: acid gas HCl     Ca(OH)<sub>2sub>     dry adsorption     high temperature     dual-layer granular bed filter    

Test of and evaluation on elevation of coalbed methane recovery ratio by injecting and burying CO<sub>2sub> for 3# coal seam of north section of Shizhuang, Qingshui Basin, Shanxi

Ye Jianping,Zhang Bing,Sam Wong

Strategic Study of CAE 2012, Volume 14, Issue 2,   Pages 38-44

Abstract: of CO2 is thought applicable for north block, Shizhuang.The gas production after injection is 2.45 times of that before injection as shown by on-site test.After injection of CO2, the coal rock swells and the local coal seam get less penetration ratio, whichinjection in the target coal seam.The test result proves that extraction of coalbed methane by CO2 injection can realize burial of CO2

Keywords: Qingshui Basin     Shanxi     CO<sub>2sub> injection     coalbed methane     recovery ratio    

Emission components characteristics of a bi-fuel vehicle at idling condition

Sameh M. METWALLEY, Shawki A. ABOUEL-SEOUD, Abdelfattah M. FARAHAT

Frontiers in Energy 2011, Volume 5, Issue 3,   Pages 322-329 doi: 10.1007/s11708-011-0158-6

Abstract: Two different fuel injection systems (i.e., multi-point injection (MPI)-sequential and closed-loop venturi-continuous

Keywords: road vehicle engine     fuel injection systems     carbon monoxide (CO)     carbon dioxide (CO<sub>2sub>)     total    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords: Mn promotion     nickel catalysts     CO<sub>2sub> methanation     co-methanation of CO and CO<sub>2sub>    

A Storage-Driven CO<sub>2sub> EOR for a Net-Zero Emission Target Article

Yueliang Liu, Zhenhua Rui

Engineering 2022, Volume 18, Issue 11,   Pages 79-87 doi: 10.1016/j.eng.2022.02.010

Abstract: >2sub>) emissions.>2sub> emissions by storing CO<sub>2sub> in oil reservoirs.CO<sub>2sub> EOR—whose main target is to realize net-zero or even negative CO<sub>2sub> emissionsStorage-driven CO<sub>2sub> EOR is superior to conventional CO<sub>2sub> EOR in improving sweepingthan conventional CO<sub>2sub> EOR.

Keywords: CO<sub>2sub>     EOR     Net CO<sub>2sub>     emissions     Dimethyl ether     Storage-driven CO<sub>2sub>     EOR     CO<sub>2sub>     sequestration    

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords: CO<sub>2sub> capture     MgO sorbents     Al<sub>2sub>O<sub>3sub>     CeO<sub>2sub>     flue gas    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: it in photocatalytic N<sub>2sub> immobilization.>2sub>WO<sub>6sub> composite.>2sub>WO<sub>6sub>.>2sub>WO<sub>6sub>, respectively.>2sub>-to-NH<sub>3sub> conversion.

Keywords: Bi<sub>2sub>WO<sub>6sub>     Cu doping     work function     photocatalytic N<sub>2sub> fixation     charge    

ZnFe<sub>2sub>O<sub>4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO<sub>2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2,   Pages 197-204 doi: 10.1007/s11705-016-1606-y

Abstract: ZnFe O -BiOCl composites were prepared by both hydrothermal and direct precipitation processes and the structures and properties of the samples were characterized by various instrumental techniques. The samples were then used as catalysts for the photocatalytic reduction of CO in cyclohexanol under ultraviolet irradiation to give cyclohexanone (CH) and cyclohexyl formate (CF). The photocatalytic CO reduction activities over the hydrothermally prepared ZnFe O -BiOCl composites were higher than those over the directly-precipitated composites. This is because compared to the direct-precipitation sample, the ZnFe O nanoparticles in the hydrothermal sample were smaller and more uniformly distributed on the surface of BiOCl and so more heterojunctions were formed. Higher CF and CH yields were obtained for the pure BiOCl and BiOCl composite samples with more exposed (001) facets than for the samples with more exposed (010) facets. This is due to the higher density of oxygen atoms in the exposed (001) facets, which creates more oxygen vacancies, and thereby improves the separation efficiency of the electron-hole pairs. More importantly, irradiation of the (001) facets with ultraviolet light produces photo-generated electrons which is helpful for the reduction of CO to ·CO . The mechanism for the photocatalytic reduction of CO in cyclohexanol over ZnFe O -BiOCl composites with exposed (001) facets involves electron transfer and carbon radical formation.

Keywords: reduction of CO<sub>2sub>     cyclohexanol     ZnFe<sub>2sub>O<sub>4sub> deposited BiOCl     facet     composite    

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Strategic Study of CAE 2013, Volume 15, Issue 2,   Pages 107-112

Abstract: The structure of SOEC, the recent development of high temperature steam/CO2 co-electrolysis from

Keywords: SOEC     H<sub>2sub>O/CO<sub>2sub> co-electrolysis     syngas     electrolysis efficiency     water electrolysis    

Title Author Date Type Operation

Frontier science and challenges on offshore carbon storage

Journal Article

Economic Development Models of Gas Condensate Reservoir

Liu Tingyuan

Journal Article

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

Journal Article

Experimental study on the CO<sub>2sub> foam injecting way of profile control and flooding in heterogeneous

Zhao Jinsheng,Tan Junling,Gu Zhengfu,Liu Xiaochun

Journal Article

Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

Journal Article

Test of and evaluation on elevation of coalbed methane recovery ratio by injecting and burying CO<sub>2sub> for 3# coal seam of north section of Shizhuang, Qingshui Basin, Shanxi

Ye Jianping,Zhang Bing,Sam Wong

Journal Article

Emission components characteristics of a bi-fuel vehicle at idling condition

Sameh M. METWALLEY, Shawki A. ABOUEL-SEOUD, Abdelfattah M. FARAHAT

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

A Storage-Driven CO<sub>2sub> EOR for a Net-Zero Emission Target

Yueliang Liu, Zhenhua Rui

Journal Article

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article

Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Journal Article

ZnFe<sub>2sub>O<sub>4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO<sub>2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Journal Article

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Journal Article